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Xinyue Zhang, Yuqiao Zhang, Fan Yang, Jianming Zhang, Yong Liu, Shun Li. Magnetic field driven catalysis of multiferroic magnetoelectric nanocomposites[J]. Materials Lab. doi: 10.54227/mlab.20230025
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Magnetic field driven catalysis of multiferroic magnetoelectric nanocomposites
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Abstract
Magnetic field as a booster for catalytic reactions has been widely studied in the past few decades. Recently, multiferroic materials with intriguing magnetoelectric coupling effects have been emerging as a new type of catalyst, providing a unique opportunity for magnetically-driven catalytic reactions in a variety of fields, including clean energy, environmental and biomedical applications. In this review, we describe this entirely new catalysis phenomenon observed in multiferroic magnetoelectric composite materials, aiming at giving an in-depth understanding of magnetically-driven catalysis processes based on the direct magnetoelectric-catalytic effect. Moreover, the latest progress in catalytic applications of magnetoelectric nanocomposite nanomaterials is comprehensively summarized. Finally, the challenges and future perspectives for the design and application of high-efficient magneto-multiferroic catalysts are discussed.
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Keywords:
- Catalysis /
- Magnetic field /
- Multiferroics /
- Magnetoelectric coupling /
- Nanocomposites
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Author Biographies
Xinyue Zhang received her Ph.D. degree at the Northeastern University in China in 2022. Her research interests include the synthesis of advanced nanomaterials and their application in the field of environmental remediation. 
Yong Liu received his Ph.D. degree at the University of Science and Technology Beijing (USTB) in 2012. His major interests focus on the R&D of novel functional materials. He investigated a variety of thermoelectrics oxide using different synchrotron radiation techniques. He published more than 30 peer reviewed articles in renowned journals, including Adv. Energy Mater., J. Am. Chem. Soc., Chem. Comm., and J. Am. Ceram. Soc. Dr. 
Shun Li is Jinshan distinguished professor of Jiangsu University. He received his B.E. Degree at Tianjin University and Ph.D. Degree at Institut national de la recherche scientifique (INRS), Canada. His research interests focus on harvesting solar/mechanical/thermal energy to chemical energy for diverse catalytic applications. He has published over 80 peer reviewed articles in prestigious international journals including Progress in Materials Science, Nano Energy, Materials Horizons, Small, etc. -
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Received Date:
26 May 2023
Accepted Date:
16 June 2023
Available Online:
04 July 2023
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Xinyue Zhang, Yuqiao Zhang, Fan Yang, Jianming Zhang, Yong Liu, Shun Li. Magnetic field driven catalysis of multiferroic magnetoelectric nanocomposites[J]. Materials Lab. doi: 10.54227/mlab.20230025
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Figure 1.
Representative applications of multiferroic magnetoelectric nanocomposites in catalysis driven by magnetic fields.
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Figure 2.
a Hydrogen evolution curves of multiferroic CFO/BFO composites under an AC magnetic field. Influence of b frequency and c intensity of applied magnetic field on hydrogen evolution. d Calculated BFO (001) slabs and schematic diagrams of the band bending caused by the reversal of the polarization for up- or down-polarization states. e Proposed mechanisms for the polarization reversal by magnetoelectric coupling in the core–shell CFO/BFO nanoparticles for driving hydrogen production reaction.[32] Copyright 2022, Wiley-VCH.
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Figure 3.
a Mechanism illustration/experimental probing and COMSOL simulations for the magnetostrictive-piezoelectric catalytic effect under magnetic field over CFO/BFO nanocomposites.[35] Copyright 2021, American Chemical Society. b Schematic illustration of the fabrication process of biodegradable soft helical microswimmers based on CFO/BFO nanocomposites and the corresponding optical image.[83] Copyright 2020, Wiley-VCH. c Schematic illustration of magnetoelectric-catalytic dissociation of Alzheimer’s Aβ aggregate structure using CFO/BFO nanoparticles under a low-frequency magnetic field.[34] Copyright 2022, Science.
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Figure 4.
a Digital and SEM image of ZnO nanorods array grown on a Metglas foil. b Kinetic rate for the degradation of indigo carmine under different conditions. c The magnetic flux density distribution in ZnO nanorods and Metglas under uniform magnetic field, and d the magnetoelectric potential distribution in a single ZnO nanorod under lateral deformation. e Schematic illustration of the magnetoelectric-photocatalytic mechanism for organic pollutant degradation process.[88] Copyright 2023, Elsevier.
