Bi(2-x)SbxTe3 Thermoelectric Composites with High Average zT Values: From Materials to Devices

Zhiliang Li; Xiaofeng Yang; Qing Wang; Hongxia Zhang; Zhihai Ding; Qian Cao; Xin Qian; Jianglong Wang; Shufang Wang

doi:10.54227/mlab.20220026

Article navigation > Materials Lab > 2022 > 1, 220026

Zhiliang Li, Xiaofeng Yang, Qing Wang, Hongxia Zhang, Zhihai Ding, et al. Bi(2-x)SbxTe3 Thermoelectric Composites with High Average zT Values: From Materials to Devices. Materials Lab 2022, 1, 220026. doi: 10.54227/mlab.20220026

Citation:

Zhiliang Li, Xiaofeng Yang, Qing Wang, Hongxia Zhang, Zhihai Ding, et al. Bi_(2-x)Sb_xTe₃ Thermoelectric Composites with High Average zT Values: From Materials to Devices. Materials Lab 2022, 1, 220026. doi: 10.54227/mlab.20220026

Research Article

Bi_(2-x)Sb_xTe₃ Thermoelectric Composites with High Average zT Values: From Materials to Devices

More Information

1.
Key Laboratory of High-Precision Computation and Application of Quantum Field Theory of Hebei Province, College of Physics Science and Technology, Hebei University, Baoding 071002, China
2.
Huabei Cooling Device Co., Ltd, Xianghe 065400, China
3.
Institute of Life Science and Green Development, Hebei University, Baoding 071002, China
Corresponding author: sfwang@hbu.edu.cn

Abstract

Abstract

(Bi,Sb)Te-based materials have drawn extensive attention for nearly two centuries as one of the most successful commercial thermoelectric (TE) materials. However, Bi_(2-x)Sb_xTe₃ composites with remarkable average figure of merit (zT_avg) values are highly desired in terms of the great contribution on expanding the applying temperature ranges of the commercial devices. Herein, Bi_0.35Sb_1.65Te₃ compound with outstanding zT_avg value of about 1.18 (integrate from 298 to 498 K) was obtained via delaying the bipolar effect by precipitating multi-scale Sb₂Te₃ inclusions. The power factor (PF) was enhanced from 2.1×10⁻³Wm⁻¹K⁻² (Bi_0.5Sb_1.5Te₃) to 4.3×10⁻³Wm⁻¹K⁻² (Bi_0.35Sb_1.65Te₃) by optimizing the carrier concentration from 1.9×10¹⁹cm⁻³ to 3.9×10¹⁹ cm⁻³ via adjusting the proportions of Bi:Sb. Correspondingly, the lattice thermal conductivities ($ {\kappa }_{l} $) were distinctly suppressed by the additional multiple phonon scattering resulting from the Sb₂Te₃ precipitates. Consequently, a remarkable zT_max, as high as ~1.35 at 373 K was obtained in the Bi_0.35Sb_1.65Te₃ sample. The temperature difference ($ \Delta $T, 6.0 A current) of the TE device that assembled with the commercial N-type Bi(Te,Se) ingot has reached up to 66.9 K. The high zT_avg, zT_max and $ \Delta $T values will further promote the commercial applications of (Bi,Sb)Te-based materials in a wide temperature range.
- Thermoelectric performance /
- Average figure of merit /
- Bismuth telluride /
- Nano-inclusion /
- Thermoelectric device
Information

Received Date: 17 April 2022

Accepted Date: 25 April 2022

Publish Date: 12 July 2022

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References

1.	L. E. Bell, Science, 2008, 321, 1457 CrossRef Google Scholar
2.	A. F. Ioffe, L. S. Stil'bans, E. K. Iordanishvili, T. S. Stavitskaya and A. G. Vineyard, Phys. Today, 1959, 12, 42 CrossRef Google Scholar
3.	X. Lu, P. Jiang, X. Bao, Nat. Commun., 2019, 10, 1 CrossRef Google Scholar
4.	G. J. Snyder, E. S. Toberer, Nat. Mater., 2008, 7, 105 CrossRef Google Scholar
5.	Y. Pei, X. Shi, A. LaLonde, H. Wang, L. Chen, G. J. Snyder, Nature, 2011, 473, 66 CrossRef Google Scholar
6.	F. J. Disalvo, Science, 1999, 285, 703 CrossRef Google Scholar
7.	J. P. Heremans, V. Jovovic, E. S. Toberer, A. Saramat, K. Kurosaki, A. Charoenphakdee, S. Yamanaka, G. J. Snyder, Science, 2008, 321, 554 CrossRef Google Scholar
8.	B. Poudel, Q. Hao, Y. Ma, Y. Lan, A. Minnich, B. Yu, X. Yan, D. Wang, A. Muto, D. Vashaee, X. Chen, J. Liu, M. S. Dresselhaus, G. Chen, Z. Ren, Science, 2008, 320, 634 CrossRef Google Scholar
9.	X. Zhang, D. Wang, H. Wu, M. Yin, Y. Pei, S. Gong, L. Huang, S. J. Pennycook, J. He, L.-D. Zhao, Energy Environ. Sci., 2017, 10, 2420 CrossRef Google Scholar
10.	Q. Zhang, Q. Zhang, S. Chen, W. Liu, K. Lukas, X. Yan, H. Wang, D. Wang, C. Opeil, G. Chen, Z. Feng, Nano Energy, 2012, 1, 183 CrossRef Google Scholar
11.	X. Chen, L. Liu, Y. Dong, L. Wang, L. Chen, W. Jiang, Prog. Nat. Sci-mater., 2012, 22, 201 CrossRef Google Scholar
12.	L. Hu, T. Zhu, X. Liu, X. Zhao, Adv. Funct. Mater., 2014, 24, 5211 CrossRef Google Scholar
13.	T. Zhu, Z. Xu, J. He, J. Shen, S. Zhu, L. Hu, T. M. Tritt, X. Zhao, J. Mater. Chem. A, 2013, 1, 11589 CrossRef Google Scholar
14.	J.-J. Shen, T.-J. Zhu, X.-B. Zhao, S.-N. Zhang, S.-H. Yang, Z.-Z. Yin, Energy Environ. Sci., 2010, 3, 1519 CrossRef Google Scholar
15.	L.-P. Hu, T.-J. Zhu, Y.-G. Wang, H.-H. Xie, Z.-J. Xu, X.-B. Zhao, Npg Asia Mater., 2014, 6, e88 CrossRef Google Scholar
16.	Z. J. Xu, L. P. Hu, P. J. Ying, X. B. Zhao, T. J. Zhu, Acta Mater., 2015, 84, 385 CrossRef Google Scholar
17.	J. Jiang, L.-D. Chen, S. Bai, Q. Yao, Q. Wang, Scripta Mater., 2005, 52, 347 CrossRef Google Scholar
18.	R. Deng, X. Su, Z. Zheng, L. Wei, Y. Yan, Q. Zhang, V. P. Dravid, C. Uher, M. G. Kanatzidis, X. Tang, Sci. Adv., 2018, 4, eaar5606 CrossRef Google Scholar
19.	Y. Pan, U. Aydemir, J. A. Grovogui, I. T. Witting, R. Hanus, Y. Xu, J. Wu, C.-F. Wu, F.-H. Sun, H.-L. Zhuang, J.-F. Dong, J.-F. Li, V. P. Dravid, G. J. Snyder, Adv. Mater., 2018, 30, 1802016 CrossRef Google Scholar
20.	Y. Pan, Y. Qiu, I. Witting, L. Zhang, C. Fu, J.-W. Li, Y. Huang, F.-H. Sun, J. He, G. J. Snyder, C. Felser, J.-F. Li, Energ. Environ. Sci, 2019, 12, 624 CrossRef Google Scholar
21.	H.-L. Zhuang, J. Pei, B. Cai, J. Dong, H. Hu, F.-H. Sun, Y. Pan, G. J. Snyder, J.-F. Li, Adv. Funct. Mater., 2021, 31, 2009681 CrossRef Google Scholar
22.	Y. Q. Cao, T. J. Zhu, X. B. Zhao, X. B. Zhang, J. P. Tu, Appl. Phys. A, 2008, 92, 321 CrossRef Google Scholar
23.	Y. Q. Cao, X. B. Zhao, T. J. Zhu, X. B. Zhang, J. P. Tu, Appl. Phys. Lett., 2008, 92, 143106 CrossRef Google Scholar
24.	S. Cao, Z.-Y. Huang, F.-Q. Zu, J. Xu, L. Yang, Z.-G. Chen, Acs Appl. Mater. Inter., 2017, 9, 36478 CrossRef Google Scholar
25.	Z.-Y. Huang, H. Zhang, L. Yang, B. Zhu, K. Zheng, M. Hong, Y. Yu, F.-Q. Zu, J. Zou, Z.-G. Chen, Mater. Today Energy, 2018, 9, 383 CrossRef Google Scholar
26.	Y. Zheng, H. Xie, Q. Zhang, A. Suwardi, X. Cheng, Y. Zhang, W. Shu, X. Wan, Z. Yang, Z. Liu, X. Tang, Acs Appl. Mater. Inter., 2020, 12, 36186 CrossRef Google Scholar
27.	W. Xie, J. He, H. J. Kang, X. Tang, S. Zhu, M. Laver, S. Wang, J. R. D. Copley, C. M. Brown, Q. Zhang, T. M. Tritt, Nano Lett., 2010, 10, 3283 CrossRef Google Scholar
28.	J. Qiu, Y. Yan, H. Xie, T. Luo, F. Xia, L. Yao, M. Zhang, T. Zhu, G. Tan, X. Su, J. Wu, C. Uher, H. Jiang, X. Tang, Sci. China Mater., 2021, 64, 1507 CrossRef Google Scholar
29.	G. Zheng, X. Su, H. Xie, Y. Shu, T. Liang, X. She, W. Liu, Y. Yan, Q. Zhang, C. Uher, M. G. Kanatzidis, X. Tang, Energy Environ. Sci., 2017, 10, 2638 CrossRef Google Scholar
30.	H. Huang, J. Li, S. Chen, Z. Zhang, Y. Yan, X. Su, X. Tang, J. Solid State Chem., 2020, 288, 121433 CrossRef Google Scholar
31.	J.-Z. Xin, C.-G. Fu, W.-J. Shi, G.-W. Li, G. Auffermann, Y.-P. Qi, T.-J. Zhu, X.-B. Zhao, C. Felser, Rare Metals, 2018, 37, 274 CrossRef Google Scholar
32.	Q. Zhang, R. Zhai, T. Fang, K. Xia, Y. Wu, F. Liu, X. Zhao, T. Zhu, J. Alloys Compd., 2020, 831, 154732 CrossRef Google Scholar
33.	F. Hao, P. Qiu, Y. Tang, S. Bai, T. Xing, H.-S. Chu, Q. Zhang, P. Lu, T. Zhang, D. Ren, J. Chen, X. Shi, L. Chen, Energy Environ. Sci., 2016, 9, 3120 CrossRef Google Scholar
34.	M. Tan, W.-D. Liu, X.-L. Shi, J. Shang, H. Li, X. B. Liu, L. Z. Kou, M. Dargusch, Y. Deng, Z.-G. Chen, Nano Energy, 2020, 78, 105379 CrossRef Google Scholar
35.	Y. Wang, M. Hong, W.-D. Liu, X.-L. Shi, S.-D. Xu, Q. Sun, H. Gao, S. Y. Lu, J. Zou, Z.-G. Chen, Chem. Eng. J., 2020, 397, 125360 CrossRef Google Scholar
36.	M. Tan, X.-L. Shi, W.-D. Liu, M. Li, Y. L. Wang, H. Li, Y. Deng, Z.-G. Chen, Adv. Energy Mater., 2021, 11, 2102578 CrossRef Google Scholar
37.	Y. Zhang, G. Xu, J. Mi, F. Han, Z. Wang, C. Ge, Mater. Res. Bull., 2011, 46, 760 CrossRef Google Scholar
38.	X. Fan, X. Cai, X. Han, C. Zhang, Z. Rong, F. Yang, G. Li, J. Solid State Chem., 2016, 233, 186 CrossRef Google Scholar
39.	M. Scheele, N. Oeschler, I. Veremchuk, K.-G. Reinsberg, A.-M. Kreuziger, A. Kornowski, J. Broekaert, C. Klinke, H. Weller, Acs Nano, 2010, 4, 4283 CrossRef Google Scholar
40.	C. Zhang, Z. Peng, Z. Li, L. Yu, K. A. Khor, Q. Xiong, Nano Energy, 2015, 15, 688 CrossRef Google Scholar
41.	M. Hong, Z. Chen, L. Yang, J. Zou, Nano Enerey, 2016, 20, 144 CrossRef Google Scholar
42.	T. Fang, X. Li, C. Hu, Q. Zhang, J. Yang, W. Zhang, X. Zhao, D. J. Singh, T. Zhu, Adv. Funct. Mater., 2019, 29, 1900677 CrossRef Google Scholar
43.	H.-J. Zhou, G.-W. Yang, Y.-Y. Zhang, Z.-K. Xu, G.-P. Wu, Acs Nano, 2018, 12, 11471 CrossRef Google Scholar
44.	A. Kanatzi, C. Papageorgiou, C. Lioutas, T. Kyratsi, J. Electron. Mater., 2013, 42, 1652 CrossRef Google Scholar
45.	B. Cai, H.-L. Zhuang, Q. Cao, H. Hu, J. Dong, Asfandiyar, J.-F. Li, Acs Appl. Mater. Inter., 2020, 12, 16426 CrossRef Google Scholar
46.	C. Li, S. Ma, P. Wei, W. Zhu, X. Nie, X. Sang, Z. Sun, Q. Zhang, W. Zhao, Energy Environ. Sci., 2020, 13, 535 CrossRef Google Scholar
47.	B. Gary, B. Phil, L. Jay, B. Nicholas, M. Michael, B.-C. Avram, Y. Bao, Nat. Commun., 2016, 7, 10302 CrossRef Google Scholar
48.	G. E. Bulman, E. Siivola, B. Shen, R. Venkatasubramanian, Appl. Phys. Lett., 2006, 89, 122117 CrossRef Google Scholar
49.	D. Singh, A. T. Kutbee, M. T. Ghoneim, A. M. Hussain, M. M. Hussain, Adv. Mater. Technologies., 2018, 3, 1700192 CrossRef Google Scholar
50.	Z. Bian, A. Shakouri, Appl. Phys. Lett., 2006, 89, 212101 CrossRef Google Scholar

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