Citation: | Jingxuan Chen, Xinyi Mei, Xiaoliang Zhang. Emerging Quantum Dots Spotlight on Next-Generation Photovoltaics. Materials Lab 2022, 1, 220007. doi: 10.54227/mlab.20220007 |
Semiconducting quantum dots (QDs) received considerable attention for application in optoelectronic devices, such as solar cells, photodetectors and light-emitting diodes, due to their unique fundamental properties, including solution processability, size-dependent bandgap energies, high stability and low cost. Specifically, the suitable bandgap energy of QDs with strong light absorption in the visible and near-infrared regions makes them a kind of competitive photovoltaic materials toward next-generation photovoltaics. Herein, the advantages of emerging QDs, including infrared lead sulfide QDs and perovskite QDs, are highlighted for new generation photovoltaics, and the possible challenges and opportunities approaching high-performance solar cells are also proposed.
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(a) The Shockley-Queisser theoretical efficiency limitation of singe-junction solar cells and the highest PCEs of QDSCs.[11,18-21] (b) The device structure of QDSCs. (c) The number of annual publications (from 2012 to 2021) of PbS-QD (searched using the keyword: PbS quantum dot) and PbS-QDSC (searched using the keyword: PbS quantum dot solar cell). The data were retrieved from Scopus. (d) The number of annual publications (from 2012 to 2021) of Pe-QD (searched using the keyword: perovskite quantum dot) and Pe-QDSC (searched using the keyword: perovskite quantum dot solar cell). The data were retrieved from Scopus. (e) Evolution of the certified PCEs of QDSCs (from National Renewable Energy Laboratory (NREL)).[22]