| Citation: |
Yuting Fan, Gangjian Tan. Ferroelectric Engineering Advances Thermoelectric Materials. Materials Lab 2022, 1, 220008. doi: 10.54227/mlab.20220008
|
Ferroelectric Engineering Advances Thermoelectric Materials
Published as part of the Virtual Special Issue "Merocuri Kanatzidis at 65"
-
Abstract
It is commonly believed that wide band gap ferroelectrics are electrically insulating and can hardly be promising thermoelectric materials. However, things could be different if their gaps are reduced while the ferroelectricity is well reserved. Here we propose that the exploration of narrow band gap semiconductors with ferroelectric characteristic might lead to simultaneous optimization of electrical and thermal transport properties for advanced thermoelectric materials. Narrow gap endows the materials with good dopability, which is a prerequisite for high electrical conductivity. In the meanwhile, ferroelectricity-induced Rashba band splitting and lattice softening would yield large Seebeck coefficient and low thermal conductivity, respectively. Altogether, excellent thermoelectric performance can be expected in the narrow gap ferroelectric semiconductors (NGFS). We also propose the design principles of potential NGFSs.
-
Keywords:
- Thermoelectrics /
- Ferroelectricity /
- Rashba effect /
- Lattice softening
-
-
Author Biographies
Yuting Fan is currently a PhD student working on thermoelectric materials at Wuhan University of Technology (WUT), under the supervision of Prof. Gangjian Tan. She received her Master degree from WUT in 2019. Her research interests focus on design and optimization of advanced GeTe-based thermoelectric materials. 
Gangjian Tan is now a full professor of materials science at Wuhan University of Technology (WUT), China. He received his Ph.D. degree from WUT in 2013. Following that, he worked as a postdoctoral research fellow at Northwestern University, Evanston till 2018. He is interested in the understanding of electron, phonon and ionic transport behaviors in solids for energy conversion and storage. He has authored over 80 peer-reviewed publications in international journals with an h-index of 39. -
References
1. J. Sun, Y. Zhang, Y. Fan, X. Tang, G. Tan, Chem. Eng. J., 2021, 431, 133699 2. B. Poudel, Q. Hao, Y. Ma, Y. Lan, A. Minnich, B. Yu, X. Yan, D. Wang, A. Muto, D. Vashaee, Science, 2008, 320, 634 3. Y. Fan, S. Xie, J. Sun, X. Tang, G. Tan, ACS Appl. Energ. Mater., 2021, 4, 6333 4. Z. Liu, W. Gao, W. Zhang, N. Sato, Q. Guo, T. Mori, Advanced Energy Materials, 2020, 10, 2002588 5. G. Xie, Z. Li, T. Luo, H. Bai, J. Sun, Y. Xiao, L.-D. Zhao, J. Wu, G. Tan, X. Tang, Nano Energy, 2020, 69, 104395 6. B. Qin, L-D. Zhao, Mat. Lab, 2022, 1, 220004 7. G. Tan, L.-D. Zhao, M. G. Kanatzidis, Chem. Rev., 2016, 116, 12123 8. G. Chen, Phys. Rev. B, 1998, 57, 14958 9. M. S. Dresselhaus, G. Chen, M. Y. Tang, R. Yang, H. Lee, D. Wang, Z. Ren, J. P. Fleurial, P. Gogna, Adv. Mater., 2007, 19, 1043 10. W. Liu, X. Tan, K. Yin, H. Liu, X. Tang, J. Shi, Q. Zhang, C. Uher, Phys. Rev. Lett., 2012, 108, 166601 11. J. P. Heremans, B. Wiendlocha, A. M. Chamoire, Energ. Environ. Sci., 2012, 5, 5510 12. G. Tan, F. Shi, S. Hao, H. Chi, L.-D. Zhao, C. Uher, C. Wolverton, V. P. Dravid, M. G. Kanatzidis, J. Am. Chem. Soc., 2015, 137, 5100 13. H. Liu, X. Shi, F. Xu, L. Zhang, W. Zhang, L. Chen, Q. Li, C. Uher, T. Day, G. J. Snyder, Nat. Mater., 2012, 11, 422 14. B. Jiang, Y. Yu, J. Cui, X. Liu, L. Xie, J. Liao, Q. Zhang, Y. Huang, S. Ning, B. Jia, Science, 2021, 371, 830 15. D. Nita, Mat. Lab, 2022, 1, 220001 16. B. Yu, M. Zebarjadi, H. Wang, K. Lukas, H. Wang, D. Wang, C. Opeil, M. Dresselhaus, G. Chen, Z. Ren, Nano Lett., 2012, 12, 2077 17. W. Zhao, Z. Liu, P. Wei, Q. Zhang, W. Zhu, X. Su, X. Tang, J. Yang, Y. Liu, J. Shi, Nat. Nanotech., 2017, 12, 55 18. L.-D. Zhao, J. He, D. Berardan, Y. Lin, J.-F. Li, C.-W. Nan, N. Dragoe, Energ. Environ. Sci., 2014, 7, 2900 19. L.-D. Zhao, S.-H. Lo, Y. Zhang, H. Sun, G. Tan, C. Uher, C. Wolverton, V. P. Dravid, M. G. Kanatzidis, Nature, 2014, 508, 373 20. I. Kudman, J. Mater. Sci., 1972, 7, 1027 21. A. Majumdar, Science, 2004, 303, 777 22. J. P. Heremans, V. Jovovic, E. S. Toberer, A. Saramat, K. Kurosaki, A. Charoenphakdee, S. Yamanaka, G. J. Snyder, Science, 2008, 321, 554 23. Y. Pei, X. Shi, A. LaLonde, H. Wang, L. Chen, G. J. Snyder, Nature, 2011, 473, 66 24. O. Delaire, J. Ma, K. Marty, A. F. May, M. A. McGuire, M.-H. Du, D. J. Singh, A. Podlesnyak, G. Ehlers, M. Lumsden, Nat. Commun., 2011, 10, 614 25. X. Meng, S. Chen, H. Peng, H. Bai, S. Zhang, X. Su, G. Tan, G. Van Tendeloo, Z. Sun, Q. Zhang, X. Tang, J. Wu, Sci. China. Mater., 2022, 1 26. Y. Xu, Ferroelectric materials and their applications, Elsevier, North Holland, 2013 27. J. F. Scott, Science, 2007, 315, 954 28. C. Bowen, H. Kim, P. Weaver, S. Dunn, Energ. Environ. Sci., 2014, 7, 25 29. Đ. Dangić, A. R. Murphy, É. D. Murray, S. Fahy, I. Savić, Phys. Rev. B, 2018, 97, 224106 30. Q. Tian, W. Zhang, Z. Qin, G. Qin, Nanoscale, 2021, 13, 18032 31. J. He, T. M. Tritt, Science, 2017, 357, eaak9997 32. O. Kvyatkovskii, Phys. Solid State, 1997, 39, 602 33. D. Sarkar, T. Ghosh, S. Roychowdhury, R. Arora, S. Sajan, G. Sheet, U. V. Waghmare, K. Biswas, J. Am. Chem. Soc., 2020, 142, 12237 34. A. Vasdev, M. Dutta, S. Mishra, V. Kaur, H. Kaur, K. Biswas, G. Sheet, Sci. Rep., 2021, 11, 17190 35. T. Xing, C. Zhu, Q. Song, H. Huang, J. Xiao, D. Ren, M. Shi, P. Qiu, X. Shi, F. Xu, L. Chen, Adv. Mater., 2021, 33, 2008773 36. X. Li, Y. Sheng, L. Wu, S. Hu, J. Yang, D. J. Singh, J. Yang, W. Zhang, npj Comput. Mater., 2020, 6, 107 37. S. Singh, A. C. Garcia-Castro, I. Valencia-Jaime, F. Muñoz, A. H. Romero, Physical Review B, 2016, 94, 161116 38. A. Banik, T. Ghosh, R. Arora, M. Dutta, J. Pandey, S. Acharya, A. Soni, U. V. Waghmare, K. Biswas, Energ. Environ. Sci., 2019, 12, 589 39. M. Hong, W. Lyv, M. Li, S. Xu, Q. Sun, J. Zou, Z.-G. Chen, Joule, 2020, 4, 2030 40. A. Narayan, Phys. Rev. B, 2015, 92, 220101 41. J. W. Bennett, K. M. Rabe, J. Solid State Chem., 2012, 195, 21 -
Rights and permissions
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Figures(4)
Information
Article Metrics
Export File
Citation
Yuting Fan, Gangjian Tan. Ferroelectric Engineering Advances Thermoelectric Materials. Materials Lab 2022, 1, 220008. doi: 10.54227/mlab.20220008
Format
Content
DownLoad:
-
Figure 1.
Strategies that boost the thermoelectric performance of hole-doped PbTe.[20-23]
-
Figure 2.
Ferroelectricity leads to Rashba band splitting and lattice instability (phonons softening).
-
Figure 3.
Simultaneous optimization of three key physical parameters (S, σ and κ) in narrow gap ferroelectric semiconductors and remarkably improved ZT values by ferroelectric engineering.
