| Citation: |
Chao Li, Yi Wu, Yi-Xin Zhang, Jun Guo, Jing Feng, et al. Bi2S3 as a Promising Thermoelectric Material: Back and Forth. Materials Lab 2022, 1, 220014. doi: 10.54227/mlab.20220014
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Bi2S3 as a Promising Thermoelectric Material: Back and Forth
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Abstract
Thermoelectric conversion technology based on thermoelectric materials can directly convert heat and electricity and is extensively used in waste heat recovery, semiconductor refrigeration, and space exploration. Currently, bismuth telluride (Bi2Te3) thermoelectric materials are the best in terms of room-temperature performance and have been commercialized. Compared with commercial Bi2Te3 thermoelectric materials of the same family (III-VI group), bismuth sulfide (Bi2S3) thermoelectric materials have the unique advantages of being abundant, low-cost, and environmentally friendly. However, the thermoelectric properties of Bi2S3 are limited by its low electrical conductivity. In recent years, with the development of preparation methods and characterization tools, many studies have emerged to improve the thermoelectric properties of Bi2S3 materials. Herein, the preparation of Bi2S3 thermoelectric materials and the implications of the process on their thermoelectric properties are summarized. The advances made in composition, structure and other strategies to optimize the thermoelectric properties of Bi2S3 are highlighted, and the current challenges for the development of Bi2S3 thermoelectric materials and potential future research directions are also discussed.
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Keywords:
- Bi2S3 /
- thermoelectric /
- nanorods /
- electrical conductivity
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Author Biographies
Chao Li is studying for his Master degree with Prof. Zhen-Hua Ge at Faculty of Materials Science and Engineering from Kunming University of Science and Technology. His research interests focus on preparation and optimization of thermoelectric materials. 
Yi Wu received his B.Eng. degree (2020) in Materials Science and Engineering from Kunming University of Science and technology under the direction of Professor Zhen-Hua Ge. His research focuses primarily on design and optimization of Bi2S3 based thermoelectric materials. 
Yi-Xin Zhang is a Ph.D student with Prof. Zhen-Hua Ge at Faculty of Materials Science and Engineering at Kunming University of Science and Technology. He received his M.E. degree in Materials Science at Kunming University of Science and Technology. His research focuses on the synthesis and characterization of chalcogenide thermoelectric materials, especially copper sulfides and copper selenides. 
Jun Guo is a Ph.D student with Prof. Zhen-Hua Ge at Faculty of Materials Science and Engineering at Kunming University of Science and Technology. His research direction is mainly focused on the design and synthesis in thermoelectric materials with high electric transport properties and/or low thermal conductivity, and effcient photocatalysts. 
Jing Feng is a full professor at Kunming University of Science and Technology. He received his Ph.D. degree in 2012 from University of Science and Technology Kunming, China. And he worked as post-doctoral researcher at University of Harvard University from 2012 to 2014. His research interests focus on ceramic thermal barrier coating material. 
Zhen-Hua Ge is a full professor at Kunming University of Science and Technology. He received his Ph.D. degree in 2013 from University of Science and Technology Beijing, China. And he worked as post-doctoral researcher at University of South Florida and Southern University of Science and Technology from February 2013 to July 2015. His research interests focus on synthesis and properties improvements of thermoelectric materials, especially for sulfides thermoelectric materials. -
References
1. D. Cahen, Mater. Today, 2008, 11, 64 2. E. Shove, Build. Res. Inf., 2018, 46, 779 3. L. Yang, Z.-G. Chen, M. S. Dargusch and J. Zou, Adv. Energy Mater., 2018, 8, 1701797 4. B. Kozinsky and D. J. Singh, Annu. Rev. Mater. Sci., 2021, 51, 565 5. G. Tan, L.-D. Zhao and M. G. Kanatzidis, Chem. Rev., 2016, 116, 12123 6. Q. Yan and M. G. Kanatzidis, Nat. Mater., 2021 7. X. Zhou, Y. Yan, X. Lu, H. Zhu, X. Han, G. Chen and Z. Ren, Mater. Today, 2018, 21, 974 8. Q. Zhu, S. Wang, X. Wang, A. Suwardi, M. H. Chua, X. Y. D. Soo and J. Xu, Nano-Micro Letters, 2021, 13, 119 9. K. Biswas, J. He, I. D. Blum, C.-I. Wu, T. P. Hogan, D. N. Seidman, V. P. Dravid and M. G. Kanatzidis, Nature, 2012, 489, 414 10. G. D. Mahan, APL Mater., 2016, 4, 104806 11. J. Mao, Z. Liu, J. Zhou, H. Zhu, Q. Zhang, G. Chen and Z. Ren, Adv. Phys., 2018, 67, 69 12. P. Qiu, X. Shi and L. Chen, Energy Stor. Mater., 2016, 3, 85 13. J.-F. Li, W.-S. Liu, L.-D. Zhao and M. Zhou, NPG Asia Mater., 2010, 2, 152 14. M. Dutta, T. Ghosh and K. Biswas, APL Mater., 2020, 8, 040910 15. M. V. Vedernikov and E. K. Iordanishvili, presented at ICT98, Nagoya, Japan (May, 1998). 16. H. Cheng, X. He, Z. Fan and J. Ouyang, Adv. Energy Mater., 2019, 9, 1901085 17. D. M. Rowe, CRC Handbook of Thermoelectrics, CRC press LLC, United States of America, 1995. 18. C. Gayner and K. K. Kar, Prog. Mater. Sci., 2016, 83, 330 19. J. L. Blackburn, A. J. Ferguson, C. Cho and J. C. Grunlan, Adv. Mater., 2018, 30, 1704386 20. V. Kozii, B. Skinner and L. Fu, Phys. Rev. B, 2019, 99, 155123 21. A. Sakai, S. Minami, T. Koretsune, T. Chen, T. Higo, Y. Wang, T. Nomoto, M. Hirayama, S. Miwa, D. Nishio-Hamane, F. Ishii, R. Arita and S. Nakatsuji, Nature, 2020, 581, 53 22. K.-i. Uchida, W. Zhou and Y. Sakuraba, Appl. Phys. Lett., 2021, 118, 140504 23. J. Xiang, S. Hu, M. Lyu, W. Zhu, C. Ma, Z. Chen, F. Steglich, G. Chen and P. Sun, Sci. China Phys. Mech., 2019, 63, 237011 24. Z. Chen, Z. Jian, W. Li, Y. Chang, B. Ge, R. Hanus, J. Yang, Y. Chen, M. Huang, G. J. Snyder and Y. Pei, Adv. Mater., 2017, 29, 1606768 25. Z.-Z. Luo, S. Cai, S. Hao, T. P. Bailey, Y. Luo, W. Luo, Y. Yu, C. Uher, C. Wolverton, V. P. Dravid, Z. Zou, Q. Yan and M. G. Kanatzidis, Energy Environ. Sci., 2022, 15, 368 26. Y.-K. Zhu, P. Wu, J. Guo, Y. Zhou, X. Chong, Z.-H. Ge and J. Feng, Ceram. Int., 2020, 46, 14994 27. C. Li, S.-H. Li, Y.-X. Zhang, J. Feng and Z.-H. Ge, J. Eur. Ceram. Soc., 2022, 42, 485 28. Z.-H. Ge, L.-D. Zhao, D. Wu, X. Liu, B.-P. Zhang, J.-F. Li and J. He, Mater. Today, 2016, 19, 227 29. Dedi, P.-C. Lee, P.-C. Wei and Y.-Y. Chen, Nanomaterials, 2021, 11, 819 30. R. Guehne, G. V. M. Williams, S. V. Chong and J. Haase, J. Phys. Chem. C, 2021, 125, 6743 31. J. Guo, Y.-X. Zhang, Z.-Y. Wang, F. Zheng, Z.-H. Ge, J. Fu and J. Feng, Nano Energy, 2020, 78, 105227 32. M. P. Deshpande, P. N. Sakariya, S. V. Bhatt, N. Garg, K. Patel and S. H. Chaki, Materials Science in Semiconductor Processing, 2014, 21, 180 33. Z. Kebbab, N. Benramdane, M. Medles, A. Bouzidi and H. Tabet-Derraz, Sol. Energy Mater. Sol. Cells, 2002, 71, 449 34. L.-L. Long, J.-J. Chen, X. Zhang, A.-Y. Zhang, Y.-X. Huang, Q. Rong and H.-Q. Yu, NPG Asia Mater., 2016, 8, e263 35. W. Luo, F. Li, Q. Li, X. Wang, W. Yang, L. Zhou and L. Mai, ACS Appl. Mater. Interfaces, 2018, 10, 7201 36. J. Ni, Y. Zhao, T. Liu, H. Zheng, L. Gao, C. Yan and L. Li, Adv. Energy Mater., 2014, 4, 1400798 37. Y. Zhao, T. Liu, H. Xia, L. Zhang, J. Jiang, M. Shen, J. Ni and L. Gao, J. Mater. Chem. A, 2014, 2, 13854 38. B. Zhang, X. Ye, W. Hou, Y. Zhao and Y. Xie, J. Phys. Chem. B, 2006, 110, 8978 39. Y. Jin, C. Tang, J. Tian and B. Shao, Bioconjug. Chem., 2021, 32, 161 40. S. Yang, Y. Zhang, S. Lu, L. Liu, L. Yang, Y. Guo, S. Yu and H. Yang, Colloids Surf. B, 2020, 196, 111291 41. Y. Zhao, Y. Tao, Q. Huang, J. Huang, J. Kuang, R. Gu, P. Zeng, H.-Y. Li, H. Liang and H. Liu, Chemosensors, 2022, 10, 48 42. Z. Li, K. Ai, Z. Yang, T. Zhang, J. Liu and X. Cui, RSC Adv., 2017, 7, 29672 43. L. F. Lundegaard, E. Makovicky, T. Boffa-Ballaran and T. Balic-Zunic, Phys. Chem. Miner., 2005, 32, 578 44. H. T. Shaban, M. M. Nassary and M. S. El-Sadek, Physica B Condens. Matter, 2008, 403, 1655 45. Z. H. Ge, B. P. Zhang, P. P. Shang and J. F. Li, J. Mater. Chem., 2011, 21, 9194 46. J. Guo, J. Yang, Z.-H. Ge, B. Jiang, Y. Qiu, Y.-K. Zhu, X. Wang, J. Rong, X. Yu, J. Feng and J. He, Adv. Funct. Mater., 2021, 31, 2102838 47. R. Chmielowski, D. Pere, C. Bera, I. Opahle, W. J. Xie, S. Jacob, F. Capet, P. Roussel, A. Weidenkaff, G. K. H. Madsen and G. Dennler, J. Appl. Phys., 2015, 117, 125103 48. C. Li, J. Zhao, Q. Hu, Z. Liu, Z. Yu and H. Yan, J. Alloys Compd., 2016, 688, 329 49. J. Pei, L. J. Zhang, B. P. Zhang, P. P. Shang and Y. C. Liu, J. Mater. Chem. C, 2017, 5, 12492 50. W. Ji, X.-L. Shi, W.-D. Liu, H. Yuan, K. Zheng, B. Wan, W. Shen, Z. Zhang, C. Fang, Q. Wang, L. Chen, Y. Zhang, X. Jia and Z.-G. Chen, Nano Energy, 2021, 87, 106171 51. B. Chen, C. Uher, L. Iordanidis and M. G. Kanatzidis, Chem. Mater., 1997, 9, 1655 52. R. Chmielowski, D. Péré, C. Bera, I. Opahle, W. Xie, S. Jacob, F. Capet, P. Roussel, A. Weidenkaff, G. K. H. Madsen and G. Dennler, J. Appl. Phys., 2015, 117, 125103 53. N. Mahuli, D. Saha and S. K. Sarkar, J. Phys. Chem. C, 2017, 121, 8136 54. D. S. Sanditov and V. N. Belomestnykh, Technical Physics, 2011, 56, 1619 55. H. Koc, H. Ozisik, E. Deligöz, A. M. Mamedov and E. Ozbay, J. Mol. Model., 2014, 20, 2180 56. X. Liu, D. Wang, H. Wu, J. Wang, Y. Zhang, G. Wang, S. J. Pennycook and L.-D. Zhao, Adv. Funct. Mater., 2019, 29, 1806558 57. L.-D. Zhao, J. He, D. Berardan, Y. Lin, J.-F. Li, C.-W. Nan and N. Dragoe, Energy Environ. Sci., 2014, 7, 2900 58. Y. Xiao, C. Chang, Y. L. Pei, D. Wu, K. L. Peng, X. Y. Zhou, S. K. Gong, J. Q. He, Y. S. Zhang, Z. Zeng and L. D. Zhao, Phys. Rev. B, 2016, 94, 125203 59. X. Gao, M. Zhou, Y. Cheng and G. F. Ji, Philos. Mag., 2016, 96, 208 60. Y. L. Pei, C. Chang, Z. Wang, M. J. Yin, M. H. Wu, G. J. Tan, H. J. Wu, Y. X. Chen, L. Zheng, S. K. Gong, T. J. Zhu, X. B. Zhao, L. Huang, J. Q. He, M. G. Kanatzidis and L. D. Zhao, J. Am. Chem. Soc., 2016, 138, 16364 61. Y. Chen, D. Y. Wang, Y. L. Zhou, Q. T. Pang, J. W. Shao, G. T. Wang, J. F. Wang and L. D. Zhao, Front. Phys., 2019, 14, 13601 62. E. Rathore, R. Juneja, S. P. Culver, N. Minafra, A. K. Singh, W. G. Zeier and K. Biswas, Chem. Mater., 2019, 31, 2106 63. J. Yang, J. Yan, G. Liu, Z. Shi and G. Qiao, J. Eur. Ceram. Soc., 2019, 39, 1214 64. W. Liu, C. F. Guo, M. Yao, Y. Lan, H. Zhang, Q. Zhang, S. Chen, C. P. Opeil and Z. Ren, Nano Energy, 2014, 4, 113 65. R. Fortulan, S. Aminorroaya Yamini, C. Nwanebu, S. Li, T. Baba, M. J. Reece and T. Mori, ACS Appl. Energy Mater., 2022, 5, 3845 66. Z.-H. Ge, B.-P. Zhang, Z.-X. Yu and J.-F. Li, J. Mater. Res., 2011, 26, 2711 67. J. Pei, L.-J. Zhang, B.-P. Zhang, P.-P. Shang and Y.-C. Liu, J. Mater. Chem. C, 2017, 5, 12492 68. Y.-X. Zhang, Z.-H. Ge and J. Feng, J. Alloys Compd., 2017, 727, 1076 69. Z.-Y. Wang, J. Guo, J. Feng and Z.-H. Ge, J. Solid State. Chem., 2021, 297, 122043 70. A. Melnikov, Met. Powder Rep., 2016, 71, 279 71. S. M. de la Parra-Arciniega, N. A. Garcia-Gomez, L. L. Garza-Tovar, D. I. García-Gutiérrez and E. M. Sánchez, Ultrason. Sonochem., 2017, 36, 95 72. F. Chen, Y. Cao and D. Jia, J. Colloid Interface Sci., 2013, 404, 110 73. M. Ranjbar and M. A. Taher, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 2016, 46, 1801 74. J. Wu, F. Qin, G. Cheng, H. Li, J. Zhang, Y. Xie, H.-J. Yang, Z. Lu, X. Yu and R. Chen, J. Alloys Compd., 2011, 509, 2116 75. J. Guo, L. Chen, Y. Wu, J. Xu, D.-H. Lu, J. Feng and Z.-H. Ge, Chem. Comm., 2020, 56, 11839 76. Tarachand, V. Sharma, R. Bhatt, V. Ganesan and G. S, Okram, Nano Res., 2016, 9, 3291 77. J. Guo, Z.-H. Ge, F. Qian, D.-H. Lu and J. Feng, J. Mater. Sci., 2020, 55, 263 78. J. Yang, L. Yu, T. Wang, J. Yan, G. Liu, Z. Shi and G. Qiao, J. Alloys Compd., 2019, 780, 35 79. X. Du, R. Shi, Y. Guo, Y. Wang, Y. Ma and Z. Yuan, Dalton Trans., 2017, 46, 2129 80. Z. H. Ge, B. P. Zhang, Z. X. Yu, Y. Liu and J. F. Li, Acta Physica Sinica, 2012, 61, 048401 81. M. C. Barma, B. D. Long, M. F. M. Sabri, S. Ramesh, R. Saidur, S. M. Said, K. Kimura, N. H. Hai, T. D. Huy and T. B. Trung, Powder Technol., 2016, 294, 348 82. K. Biswas, L.-D. Zhao and M. G. Kanatzidis, Adv. Energy Mater., 2012, 2, 634 83. X. Qu, Z. Gao, M. Liu, H. zhai, L. Shi, Y. Li and H. Song, Appl. Surf. Sci., 2020, 501, 144047 84. Q. Yang, C. Hu, S. Wang, Y. Xi and K. Zhang, J. Phys. Chem. C, 2013, 117, 5515 85. Z.-H. Ge, P. Qin, D. He, X. Chong, D. Feng, Y.-H. Ji, J. Feng and J. He, ACS Appl. Mater. Interfaces, 2017, 9, 4828 86. H. Zhang, Y. J. Ji, X. Y. Ma, J. Xu and D. R. Yang, Nanotechnology, 2003, 14, 974 87. T. Huang, Y. Li, X. Wu, K. Lv, Q. Li, M. Li, D. Du and H. Ye, Chinese J. Catal., 2018, 39, 718 88. H. Chen, T. Huang, S. Zheng, T. Fang and L. Wang, Mater. Lett., 2016, 185, 67 89. S. Sharma, H. H. Singh, S. Kumar and N. Khare, Nanotechnology, 2021, 32, 335705 90. R. S. Lokhande, S. R. Thakur and P. A. Chate, Optik, 2020, 219, 165230 91. S. A. Patil, Y.-T. Hwang, V. V. Jadhav, K. H. Kim and H.-S. Kim, J. Photochem. Photobiol. A, 2017, 332, 174 92. H. Kim, J.-e. Park, K. Kim, M.-K. Han, S.-J. Kim and W. Lee, Chinese J. Chem., 2013, 31, 752 93. J. Arumugam, A. D. Raj, A. A. Irudayaraj and M. Thambidurai, Mater. Lett., 2018, 220, 28 94. Z.-H. Ge, B.-P. Zhang, Z.-X. Yu and B.-B. Jiang, CrystEngComm, 2012, 14, 2283 95. Z. H. Ge and G. S. Nolas, Cryst, Growth Des., 2014, 14, 533 96. Z. H. Ge, P. Qin, D. S. He, X. Y. Chong, D. Feng, Y. H. Ji, J. Feng and J. Q. He, ACS Appl. Mater. Interfaces, 2017, 9, 4828 97. A. A. Rahman, R. Huang and L. Whittaker-Brooks, Chem. Mater., 2016, 28, 6544 98. J. Wu, F. Qin, F. Y. F. Chan, G. Cheng, H. Li, Z. Lu and R. Chen, Mater. Lett., 2010, 64, 287 99. D. C. Onwudiwe, J. Nano Res., 2019, 58, 80 100. S. Ahmadi Atouei, A. A. Ranjbar andA. Rezania, Appl. Energy, 2017, 208, 332 101. J. Shi, M. Qin, W. Aftab and R. Zou, Energy Stor. Mater., 2021, 41, 321 102. Z. H. Ge, B. P. Zhang, Y. X. Chen, Z. X. Yu, Y. Liu and J. F. Li, Chem. Comm., 2011, 47, 12697 103. H. Bai, X. Su, D. Yang, Q. Zhang, G. Tan, C. Uher, X. Tang and J. Wu, Adv. Funct. Mater., 2021, 31, 2100431 104. J. Guo, Z. Y. Wang, Y. K. Zhu, L. Chen, J. Feng and Z. H. Ge, Rare Metals, 2022, 41, 931 105. Y. X. Zhang, Z. H. Ge and J. Feng, J. Alloys Compd., 2017, 727, 1076 106. W. Liu, K. C. Lukas, K. McEnaney, S. Lee, Q. Zhang, C. P. Opeil, G. Chen and Z. Ren, Energy Environ. Sci., 2013, 6, 552 107. W. Zhao, J. Ding, Y. Zou, C.-a. Di and D. Zhu, Chem. Soc. Rev., 2020, 49, 7210 108. Y. Huang, C. Chen, W. Zhang, X. Li, W. Xue, X. Wang, Y. Liu, H. Yao, Z. Zhang, Y. Chen, F. Cao, X. Liu, Y. Wang and Q. Zhang, Sci. China Mater., 2021, 64, 2541 109. B. Wang, Y. Wang, S. Zheng, S. Liu, J. Li, S. Chang, T. An, W. Sun and Y. Chen, J. Alloys Compd., 2019, 806, 676 110. S. Hiroi, S. Nishino, S. Choi, O. Seo, J. Kim, Y. Chen, C. Song, A. Tayal, O. Sakata and T. Takeuchi, J. Appl. Phys., 2019, 125, 225101 111. C.-C. Lin, R. Lydia, J. H. Yun, H. S. Lee and J. S. Rhyee, Chem. Mater., 2017, 29, 5344 112. J. L. Lensch-Falk, J. D. Sugar, M. A. Hekmaty and D. L. Medlin, J. Alloys Compd., 2010, 504, 37 113. Z. H. Ge, B. P. Zhang, Y. Liu and J. F. Li, Phys. Chem. Chem. Phys., 2012, 14, 4475 114. Z.-H. Ge, B.-P. Zhang, Y.-Q. Yu and P.-P. Shang, J. Alloys Compd., 2012, 514, 205 115. L.-J. Zhang, B.-P. Zhang, Z.-H. Ge, C.-G. Han, N. Chen and J.-F. Li, Intermetallics, 2013, 36, 96 116. Y. Q. Yu, B. P. Zhang, Z. H. Ge, P. P. Shang and Y. X. Chen, Mater. Chem. Phys., 2011, 131, 216 117. L. J. Zhang, B. P. Zhang, Z. H. Ge and C. G. Han, Solid State Commun., 2013, 162, 48 118. M. K. Han, S. Kim, H. Y. Kim and S. J. Kim, RSC Adv., 2013, 3, 4673 119. Z. Liu, Y. Pei, H. Geng, J. Zhou, X. Meng, W. Cai, W. Liu and J. Sui, Nano Energy, 2015, 13, 554 120. X. Du, R. Shi, Y. Ma, F. Cai, X. Wang and Z. Yuan, RSC Adv., 2015, 5, 31004 121. J. Yang, G. Liu, J. Yan, X. Zhang, Z. Shi and G. Qiao, Alloys Compd., 2017, 728, 351 122. Y. Guo, X. Du, Y. Wang and Z. Yuan, J. Alloys Compd., 2017, 717, 177 123. F. Fitriani, S. M. Said, S. Rozali, M. F. M. Salleh, M. F. M. Sabri, D. L. Bui, T. Nakayama, O. Raihan, M. M. I. Megat Hasnan, M. B. A. Bashir and F. Kamal, Electron. Mater. Lett., 2018, 14, 689 124. Y. Chen, D. Wang, Y. Zhou, Q. Pang, J. Shao, G. Wang, J. Wang and L.-D. Zhao, Front. Phys., 2018, 14, 13601 125. J. Yan, J. Yang, B. Ge, G. Liu, Z. Shi, Z. Duan and G. Qiao, J. Electron. Mater., 2019, 48, 503 126. Y. Wu, Q. Lou, Y. Qiu, J. Guo, Z.-Y. Mei, X. Xu, J. Feng, J. He and Z.-H. Ge, Inorg. Chem. Front., 2019, 6, 1374 127. J. Guo, Y.-K. Zhu, L. Chen, Z.-Y. Wang, Z.-H. Ge and J. Feng, J. Mater. Sci. Technol., 2022, 100, 51 128. J. Guo, Z.-Y. Wang, Y.-K. Zhu, L. Chen, J. Feng and Z.-H. Ge, Rare Metals, 2022, 41, 931 129. Z. Li, C. Xiao, H. Zhu and Y. Xie, J. Am. Chem. Soc., 2016, 138, 14810 130. T. Zhu, L. Hu, X. Zhao and J. He, Adv. Sci., 2016, 3, 1600004 131. Y. Yu, S. Zhang, A. M. Mio, B. Gault, A. Sheskin, C. Scheu, D. Raabe, F. Zu, M. Wuttig, Y. Amouyal and O. Cojocaru-Mirédin, ACS Appl. Mater. Interfaces, 2018, 10, 3609 132. Z. Chen, B. Ge, W. Li, S. Lin, J. Shen, Y. Chang, R. Hanus, G. J. Snyder and Y. Pei, Nat. Commun., 2017, 8, 13828 133. X. Meng, Z. Liu, B. Cui, D. Qin, H. Geng, W. Cai, L. Fu, J. He, Z. Ren and J. Sui, Adv. Energy Mater., 2017, 7, 1602582 134. Y. Jian, Y. Junnan, L. Guiwu, S. Zhongqi and Q. Guanjun, J. Eur. Ceram. Soc., 2019, 39, 1214 135. F. Zhang, D. Wu and J. He, Materials Lab, 2022, 1, 220012 136. J. Zhang, T. Zhu, C. Zhang, Y. Yan, G. Tan, W. Liu, X. Su and X. Tang, J. Alloys Compd., 2021, 881, 160639 137. H. Iwasaki, I. Kimura, T. Murakami and H. Kim, Physica B Condens. Matter, 2015, 472, 91 138. D. P. Wong, W. L. Chien, C. Y. Huang, C. E. Chang, A. Ganguly, L. M. Lyu, J. S. Hwang, L. C. Chen and K. H. Chen, RSC Adv., 2016, 6, 98952 139. A. Nozariasbmarz, B. Poudel, W. Li, H. B. Kang, H. Zhu and S. Priya, iScience, 2020, 23, 101340 140. I. Malik, T. Srivastava, K. K. Surthi, C. Gayner and K. K. Kar, Mater. Chem. Phys., 2020, 255, 123598 141. S. I. Kim, K. H. Lee, H. A. Mun, H. S. Kim, S. W. Hwang, J. W. Roh, D. J. Yang, W. H. Shin, X. S. Li, Y. H. Lee, G. J. Snyder and S. W. Kim, Science, 2015, 348, 109 142. L. D. Hicks and M. S. Dresselhaus, Phys. Rev. B, 1993, 47, 16631 143. B. Qin and L.-D. Zhao, Materials Lab, 2022, 1, 220004 144. J. Guo, Q. Lou, Y. Qiu, Z.-Y. Wang, Z.-H. Ge, J. Feng and J. He, Appl. Surf. Sci., 2020, 520, 146341 145. B. Xu, T. Feng, M. T. Agne, Q. Tan, Z. Li, K. Imasato, L. Zhou, J.-H. Bahk, X. Ruan, G. J. Snyder and Y. Wu, Angew. Chem. Int. Ed., 2018, 57, 2413 146. D. Li, X. Y. Qin, J. Zhang and H. J. Li, Physics Letters A, 2006, 348, 379 147. Y. Zhong, J. Tang, H. Liu, Z. Chen, L. Lin, D. Ren, B. Liu and R. Ang, ACS Appl. Mater. Interfaces, 2020, 12, 49323 148. S. Sarkar, X. Hua, S. Hao, X. Zhang, T. P. Bailey, T. J. Slade, P. Yasaei, R. J. Korkosz, G. Tan, C. Uher, V. P. Dravid, C. Wolverton and M. G. Kanatzidis, Chem. Mater., 2021, 33, 1842 149. J. P. Heremans, B. Wiendlocha and A. M. Chamoire, Energy Environ. Sci., 2012, 5, 5510 150. Z.-H. Ge, B.-P. Zhang and J.-F. Li, J. Mater. Chem., 2012, 22, 17589 151. X. Li, L. L. Xi and J. Yang, J. Inorg. Mater., 2019, 34, 236 152. Y. Iwasaki, R. Sawada, V. Stanev, M. Ishida, A. Kirihara, Y. Omori, H. Someya, I. Takeuchi, E. Saitoh and S. Yorozu, NPJ Comput. Mater., 2019, 5, 103 153. Y. Iwasaki, I. Takeuchi, V. Stanev, A. G. Kusne, M. Ishida, A. Kirihara, K. Ihara, R. Sawada, K. Terashima, H. Someya, K.-i. Uchida, E. Saitoh and S. Yorozu, Sci. Rep., 2019, 9, 2751 154. M. Hong, W. Lyu, Y. Wang, J. Zou and Z.-G. Chen, J. Am. Chem. Soc., 2020, 142, 2672 155. G. Xing, J. Sun, Y. Li, X. Fan, W. Zheng and D. J. Singh, Phys. Rev. Mater., 2017, 1, 065405 156. D. Nita, Materials Lab, 2022, 1, 220001 157. C. Xiao, K. Li, J. Zhang, W. Tong, Y. Liu, Z. Li, P. Huang, B. Pan, H. Su and Y. Xie, Mater. Horizons, 2014, 1, 81 158. L. Hu, Y. Zhang, H. Wu, J. Li, Y. Li, M. Mckenna, J. He, F. Liu, S. J. Pennycook and X. Zeng, Adv. Energy Mater., 2018, 8, 1802116 159. M. Ruan, F. Li, Y. Chen, Z. Zheng and P. Fan, J. Alloys Compd., 2020, 849, 156677 160. S.-J. Joo, B. Ryu, J.-H. Son, J. E. Lee, B.-K. Min and B.-S. Kim, J. Alloys Compd., 2019, 783, 448 161. F. Li, M. Ruan, B. Jabar, C. Liang, Y. Chen, D. Ao, Z. Zheng, P. Fan and W. Liu, Nano Energy, 2021, 88, 106273 162. B. Jabar, F. Li, Z. Zheng, A. Mansoor, Y. Zhu, C. Liang, D. Ao, Y. Chen, G. Liang, P. Fan and W. Liu, Nat. Commun., 2021, 12, 7192 -
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Received Date:
27 February 2022
Revised Date:
30 March 2022
Accepted Date:
06 April 2022
Publish Date:
12 July 2022
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Chao Li, Yi Wu, Yi-Xin Zhang, Jun Guo, Jing Feng, et al. Bi2S3 as a Promising Thermoelectric Material: Back and Forth. Materials Lab 2022, 1, 220014. doi: 10.54227/mlab.20220014
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Figure 1.
Diagram of a temperature differential power unit and a cooling unit.
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Figure 2.
(a) The abundance of various elements employed in thermoelectric materials. (b) The price of elements compared with that of 99.99% Te powder (200 mesh). (c) The LD50 values of elements normally employed in thermoelectric materials. [28]
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Figure 3.
The crystal structure of Bi2S3.
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Figure 4.
Calculated electronic band structure and projected density of states (DOS) for Bi2S3 without spin orbital coupling (SOC) considered. The vertical red lines refer to valence band maximum (VBM) and conduction band minimum (CBM). The black dashed line refers to Fermi level. [46]
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Figure 5.
Experimental measured
$ {\mathit{C}}_{\mathit{p}} $ $ {\mathit{C}}_{\mathit{p}} $ -
Figure 6.
Sample morphology and XRD patterns of Bi2S3 prepared by solid-phase melting. Reproduced with permission.[82]
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Figure 7.
Sample morphology of Bi2S3 prepared by hydrothermal method.[94]
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Figure 8.
Preparation process of Bi@Bi2S3 core-shell nanostructures. [95]
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Figure 9.
(a) Phase diagram of the Bi2Te3–Bi2Se3–Bi2S3 system. (b) Hall carrier concentration, (c) weighted mobility, and (d) lattice thermal conductivity of the Bi2Te3–Bi2Se3–Bi2S3 system. [106]
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Figure 10.
Schematic diagram of interstitial atom, vacancy, replacement atom and Secondary phase.
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Figure 11.
Diagram of the thermoelectric properties of solution halogen-doped Bi2S3. [46]
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Figure 12.
Design and physical drawing of thermoelectric power generation device prepared by solution halogen-doped Bi2S3 and its performance characteristics. Reproduced with permission.[46] Copyright 2021, Wiley-VCH.
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Figure 13.
Optimization of the thermoelectric properties of Bi2S3 by PbBr2 doping and multiple nanoprecipitates. [31]
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Figure 14.
Mechanism (a), preparation method (b) and microstructure (c) of modulated doped Bi2S3. [144]
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Figure 15.
(a) (b) Schematic diagram and microstructure of highly textured bulk Bi2S3 prepared by sintering of (001) oriented Bi2S3 nanorods prepared by the hydrothermal method. [45, 94] (c) Bi2S3 nanocomposite sintered from Bi2S3@Bi core-shell nanowires prepared by the hydrothermal method. [85].
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Figure 16.
Design, preparation and characterization of electronic fast channels. [150]
