Xinzhi Wu, Jian Huang, Zihan Zhou, Zhijia Han, Feng Jiang, Huan Li, Yupeng Wang, Kang Zhu, Weishu Liu. Mg3Sb2-based thermoelectrics: materials, interfaces, and devices[J]. Materials Lab, 2023, 2(2): 230003. doi: 10.54227/mlab.20230003
Citation: Xinzhi Wu, Jian Huang, Zihan Zhou, Zhijia Han, Feng Jiang, Huan Li, Yupeng Wang, Kang Zhu, Weishu Liu. Mg3Sb2-based thermoelectrics: materials, interfaces, and devices[J]. Materials Lab, 2023, 2(2): 230003. doi: 10.54227/mlab.20230003

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Mg3Sb2-based thermoelectrics: materials, interfaces, and devices

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  • Corresponding author: liuws@sustech.edu.cn
  • Thermoelectric power generators enable the direct conversion between waste heat and electricity near room temperatures, providing an environmentally friendly solution toward mitigating the ever-increasing global energy issues. Over the past years, we have witnessed significant advances in Mg3Sb2-based thermoelectric conversion materials. However, the device-relative efforts lag behind the materials-level works. In this mini-review, we summarize the advances in Mg3Sb2-based thermoelectrics from materials to devices. Further, we shine some light on the device-level challenge, including the design of thermoelectric interface materials, the stability issue, and the system-level full-parameter optimization. Finally, we discuss the new application scenarios exploration to inspire confidence in device-level efforts towards practical applications.


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  • Xinzhi Wu, he is a PhD candidate in southern university of science and technology, majoring in Materials Science and Engineering. His research interest focuses on thermoelectric materials and related devices.
    Liu Weishu, his research topic is room-temperature thermoelectric materials and devices. He proposed a general material parameter B* for searching new thermoelectric materials and discovered the selective enhancement effect of ionic transport in the gelatin-based ionic thermoelectric materials. He also made an exclusive contribution to wearable thermoelectric devices. He has published over 130 papers in high reputation journals, including Science, PNAS, Nat. Comm., Energy Environ. Sci., Adv. Mater. etc., and has total citations over 10000 times and H-index of 52. He has been awarded the “Tencent XPlorer Prize 2019”.
  • 1. L. E. Bell, Science, 2008, 321, 1457
    2. S. Roychowdhury, T. Ghosh, R. Arora, M. Samanta, L. Xie, N. K. Singh, A. Soni, J. Q. He, U. V. Waghmare and K. Biswas, Science, 2021, 371, 722
    3. Z. Liu, Materials Lab, 2022, 1, 220003
    4. C. Candolfi, S. E. Oualid, D. Ibrahim, S. Misra, O. E. Hamouli, A. Léon, A. Dauscher, P. Masschelein, P. Gall, P. Gougeon, C. Semprimoschnig and B. Lenoir, CEAS Space Journal, 2021, 13, 325
    5. I. Petsagkourakis, K. Tybrandt, X. Crispin, I. Ohkubo, N. Satoh and T. Mori, Sci. Technol. Adv. Mater., 2018, 19, 836
    6. M. Haras and T. Skotnicki, Nano Energy, 2018, 54, 461−476
    7. D. Champier, Energy Conversion and Management, 2017, 140, 167
    8. G. Schierning, Nat. Energy, 2018, 3, 92
    9. J. Mao, Z. H. Liu and Z. F. Ren, Science, 2019, 365, 495
    10. J. Yang, G. Li, H. Zhu, N. Chen, T. Lu, J. Gao, L. Guo, J. Xiang, P. Sun, Y. Yao, R. Yang and H. Zhao, Joule, 2021, 6, 193
    11. I. Chowdhury, R. Prasher, K. Lofgreen, G. Chrysler, S. Narasimhan, R. Mahajan, D. Koester, R. Alley and R. Venkatasubramanian, Nat. Nanotechnol., 2009, 4, 235
    12. Q. Zhang, K. Deng, L. Wilkens, H. Reith and K. Nielsch, Nature Electronics, 2022, 5, 333
    13. B. Jiang, Y. Yu, J. Cui, X. Liu, L. Xie, J. Liao, Q. Zhang, Y. Huang, S. Ning, B. Jia, B. Zhu, S. Bai, L. Chen, S. J. Pennycook and J. He, Science, 2021, 371, 830
    14. Y. F. Xing, R. H. Liu, J. C. Liao, Q. H. Zhang, X. G. Xia, C. Wang, H. Huang, J. Chu, M. Gu, T. J. Zhu, C. X. Zhu, F. F. Xu, D. X. Yao, Y. P. Zeng, S. Q. Bai, C. Uher and L. D. Chen, Energ Environ. Sci., 2019, 12, 3390
    15. Z. Bu, X. Zhang, B. Shan, J. Tang, H. Liu, Z. Chen, S. Lin, W. Li and Y. Pei, Sci Adv, 2021, 7, eabf2738
    16. B. C. Qin, D. Y. Wang, X. X. Liu, Y. X. Qin, J. F. Dong, J. F. Luo, J. W. Li, W. Liu, G. J. Tan, X. F. Tang, J. F. Li, J. Q. He and L. D. Zhao, Science, 2021, 373, 556
    17. P. F. Qiu, T. Mao, Z. F. Huang, X. G. Xia, J. C. Liao, M. T. Agne, M. Gu, Q. H. Zhang, D. D. Ren, S. Q. Bai, X. Shi, G. J. Snyder and L. D. Chen, Joule, 2019, 3, 1538
    18. P. J. Ying, R. He, J. Mao, Q. Zhang, H. Reith, J. H. Sui, Z. F. Ren, K. Nielsch and G. Schierning, Nat. Commun., 2021, 12, 1121
    19. Z. Bu, X. Zhang, Y. Hu, Z. Chen, S. Lin, W. Li, C. Xiao and Y. Pei, Nat. Commun., 2022, 13, 237
    20. Z. Liu, W. Gao, H. Oshima, K. Nagase, C. H. Lee and T. Mori, Nat. Commun., 2022, 13, 1120
    21. Jun Pei, Bowen Cai, Hua-Lu Zhuang and Jing-Feng Li, Natl Sci Rev., 2020, 7, 1856
    22. F. Jiang, T. Feng, Y. Zhu, C. Xia, C. Liu, Y. Chen and W. Liu, Materials Lab, 2022, 1, 220045
    23. H. L. Zhuang, J. Pei, B. W. Cai, J. F. Dong, H. H. Hu, F. H. Sun, Y. Pan, G. J. Snyder and J. F. Li, Adv. Funct. Mater., 2021, 31, 2009681
    24. W. S. Liu and S. Q. Bai, J. Materiomics, 2019, 5, 321
    25. W. S. Liu, Q. Jie, H. S. Kim and Z. F. Ren, Acta Mater., 2015, 87, 357
    26. C. Xu, Z. Liang, W. Ren, S. Song, F. Zhang and Z. Ren, Adv. Energy Mater., 2022, 12, 2202392
    27. Q. Zhu, S. W. Song, H. T. Zhu and Z. F. Ren, J. Power Sources, 2019, 414, 393
    28. H. J. Shang, Z. X. Liang, C. C. Xu, S. W. Song, D. X. Huang, H. W. Gu, J. Mao, Z. F. Ren and F. Z. Ding, Acta Mater., 2020, 201, 572
    29. L. Yin, C. Chen, F. Zhang, X. F. Li, F. X. Bai, Z. W. Zhang, X. Y. Wang, J. Mao, F. Cao, X. J. Chen, J. H. Sui, X. J. Liu and Q. Zhang, Acta Mater., 2020, 198, 25
    30. Z. L. Bu, X. Y. Zhang, Y. X. Hu, Z. W. Chen, S. Q. Lin, W. Li and Y. Z. Pei, Energ Environ. Sci., 2021, 14, 6506
    31. Z. Liang, C. C. Xu, H. Shang, Q. Zhu, F. Z. Ding, J. Mao and Z. F. Ren, Mater. Today Phys., 2021, 19, 100413
    32. Z. H. Liu, N. Sato, W. H. Gao, K. Yubuta, N. Kawamoto, M. Mitome, K. Kurashima, Y. Owada, K. Nagase, C.-H. Lee, J. H. Yi, K. Tsuchiya and T. Mori, Joule, 2021, 5, 1196
    33. C. C. Xu, Z. Liang, H. J. Shang, D. Wang, H. Wang, F. Z. Ding, J. Mao and Z. F. Ren, Mater. Today Phys., 2021, 17, 100336
    34. Y. Fu, Q. Zhang, Z. Hu, M. Jiang, A. Huang, X. Ai, S. Wan, H. Reith, L. Wang, K. Nielsch and W. Jiang, Energ Environ. Sci., 2022, 15, 3265
    35. S. Song, Z. Liang, C. Xu, Y. Wang, X. Shi, W. Ren and Z. Ren, Soft Science, 2022, 2, 13
    36. Y. Wang, J. Chen, Y. Jiang, M. Ferhat, S. Ohno, Z. A. Munir, W. Fan and S. Chen, ACS Appl. Mater. Interfaces, 2022, 14, 33419
    37. X. Wu, Z. Han, Y. Zhu, B. Deng, K. Zhu, C. Liu, F. Jiang and W. Liu, Acta Mater., 2022, 226, 117616
    38. P. Ying, L. Wilkens, H. Reith, N. P. Rodriguez, X. Hong, Q. Lu, C. Hess, K. Nielsch and R. He, Energ Environ. Sci., 2022, 15, 2557
    39. J. M. Tarascon and M. Armand, Nature, 2001, 414, 359
    40. Z. J. Han, J.-W. Li, F. Jiang, J. Xia, B.-P. Zhang, J.-F. Li and W. S. Liu, J. Materiomics, 2021, 8, 427
    41. J. W. Zhang, L. R. Jorgensen, L. R. Song and B. B. Iversen, ACS Appl. Mater. Interfaces, 2022, 14, 31024
    42. H. Tamaki, H. K. Sato and T. Kanno, Adv. Mater., 2016, 28, 10182
    43. M. Wood, J. J. Kuo, K. Imasato and G. J. Snyder, Adv. Mater., 2019, 31, e1902337
    44. X. M. Shi, C. Sun, Z. L. Bu, X. Y. Zhang, Y. X. Wu, S. Q. Lin, W. Li, A. Faghaninia, A. Jain and Y. Z. Pei, Adv. Sci., 2019, 6, 1802286
    45. J. S. Liang, X. L. Shi, Y. Peng, W. D. Liu, H. Q. Yang, C. Y. Liu, J. L. Chen, Q. Zhou, L. Miao and Z. G. Chen, Adv. Energy Mater., 2022, 12, 2201086
    46. R. Shu, Y. C. Zhou, Q. Wang, Z. J. Han, Y. B. Zhu, Y. Liu, Y. X. Chen, M. Gu, W. Xu, Y. Wang, W. Q. Zhang, L. Huang and W. S. Liu, Adv. Funct. Mater., 2019, 29, 1807235
    47. X. M. Shi, T. T. Zhao, X. Y. Zhang, C. Sun, Z. W. Chen, S. Q. Lin, W. Li, H. Gu and Y. Z. Pei, Adv. Mater., 2019, 31, 1970253
    48. Y. J. Liu, L. Yin, W. W. Zhang, J. Wang, S. H. Hou, Z. X. Wu, Z. W. Zhang, C. Chen, X. F. Li, H. J. Ji, Q. Zhang, Z. G. Liu and F. Cao, Cell Rep. Phys. Sci., 2021, 2, 100412
    49. X. Shi, C. Sun, X. Zhang, Z. Chen, S. Lin, W. Li and Y. Pei, Chem. Mater., 2019, 31, 8987
    50. K. Imasato, S. D. Kang and G. J. Snyder, Energ Environ. Sci., 2019, 12, 965
    51. S. Ohno, K. Imasato, S. Anand, H. Tamaki, S. D. Kang, P. Gorai, H. K. Sato, E. S. Toberer, T. Kanno and G. J. Snyder, Joule, 2018, 2, 141
    52. K. Imasato, M. Wood, J. J. Kuo and G. J. Snyder, J. Mater. Chem. A, 2018, 6, 19941
    53. M. Wood, K. Imasato, S. Anand, J. Yang and G. J. Snyder, J. Mater. Chem. A, 2020, 8, 2033
    54. F. Jiang, T. Feng, Y. Zhu, Z. Han, R. Shu, C. Chen, Y. Zhang, C. Xia, X. Wu, H. Yu, C. Liu, Y. Chen and W. Liu, Mater. Today Phys., 2022, 27, 100835
    55. Z. J. Han, Z. G. Gui, Y. B. Zhu, P. Qin, B. P. Zhang, W. Q. Zhang, L. Huang and W. S. Liu, Research, 2020, 2020, 1672051
    56. X. X. Chen, J. B. Zhu, D. D. Qin, N. Qu, W. H. Xue, Y. M. Wang, Q. Zhang, W. Cai, F. K. Guo and J. H. Sui, Sci. China Mater., 2021, 64, 1761
    57. A. F. Ioffe, Semiconductor Thermoelements and Thermoelectric Cooling, Infosearch, UK, 1956, pp 36-73.
    58. A. F. Ioffe, Physics of Semiconductors, Izd. AN SSSR, Russian, 1957.
    59. J. Zhang, L. Song, S. H. Pedersen, H. Yin, L. T. Hung and B. B. Iversen, Nat. Commun., 2017, 8, 13901
    60. X. M. Shi, T. T. Zhao, X. Y. Zhang, C. Sun, Z. W. Chen, S. Q. Lin, W. Li, H. Gu and Y. Z. Pei, Adv. Mater., 2019, 31, 1903387
    61. L. R. Jørgensen, J. Zhang, C. B. Zeuthen and B. B. Iversen, J. Mater. Chem. A, 2018, 6, 17171
    62. X. Wu, Y. Lin, Z. Han, H. Li, C. Liu, Y. Wang, P. Zhang, K. Zhu, F. Jiang, J. Huang, H. Fan, F. Cheng, B. Ge and W. Liu, Adv. Energy Mater., 2022, 12, 2203039
    63. A. R. Li, P. F. Nan, Y. C. Wang, Z. H. Gao, S. Y. Zhang, Z. K. Han, X. B. Zhao, B. H. Ge, C. G. Fu and T. J. Zhu, Acta Mater., 2022, 239, 118301
    64. K. Xiong, W. Wang, H. N. Alshareef, R. P. Gupta, J. B. White, B. E. Gnade and K. Cho, J. Phys. D: Appl. Phys., 2010, 43, 115303
    65. P. Jood, M. Ohta, A. Yamamoto and M. G. Kanatzidis, Joule, 2018, 2, 1339
    66. L. Chen, R. Liu and X. Shi, Thermoelectric Materials and Devices, 2021, 221
    67. M. Ohta, P. Jood, M. Murata, C. H. Lee, A. Yamamoto and H. Obara, Adv. Energy Mater., 2018, 9, 1801304
    68. W. S. Liu, H. Z. Wang, L. J. Wang, X. W. Wang, G. Joshi, G. Chen and Z. F. Ren, J. Mater. Chem. A, 2013, 1, 13093
    69. Y. Lin, X. Wu, Y. Li, F. Cheng, W. Liu and B. Ge, Nano Energy, 2022, 102, 107736
    70. Y. Sun, L. Yin, Z. Zhang, H. He, C. Chen, S. Li, L. Chen, J. Jia, X. Wang, J. Sui, X. Liu, J. Mao, F. Cao and Q. Zhang, Acta Mater., 2022, 235, 118066
    71. Zhongxin Liang, Liangzi Deng, Xin Shi, Shaowei Song, Congcong Xu, Ching-Wu Chu and Z. Ren, Materials Today Energy, 2022, 29, 101099
    72. P. Ying, H. Reith, K. Nielsch and R. He, Small, 2022, 18, 2201183
    73. Hi-Z Thermoelectric Generator Products, HZ-2, https://hi-z.com/, (accessed 22.09, 2022).
    74. Z. Liang, C. Xu, S. Song, X. Shi, W. Ren and Z. Ren, Adv. Funct. Mater., 2023, 33, 2210016
    75. L.-D. Zhao, B.-P. Zhang, J.-F. Li, M. Zhou, W.-S. Liu and J. Liu, J. Alloys Compd., 2008, 455, 259
    76. J.-F. Li, S. Tanaka, T. Umeki, S. Sugimoto, M. Esashi and R. Watanabe, Sensors and Actuators A: Physical, 2003, 108, 97
    77. Q. Xu, B. Deng, L. Zhang, S. Lin, Z. Han, Q. Zhou, J. Li, Y. Zhu, F. Jiang, Q. Li, P. Zhang, X. Zhang, G. Chen and W. Liu, Cell Rep. Phys. Sci., 2022, 3, 100780
    78. P. Zhang, B. Deng, K. Zhu, Q. Zhou, S. Zhang, W. Sun, Z. Zheng and W. Liu, EcoMat, 2022, 4, e12253
    79. J. C. Ordonez and C. Ordonez, 2021 IEEE Conference on Technologies for Sustainability (SusTech), Irvine, CA, USA (April 2021).
    80. L. P. R. Nadimuthu and K. Victor, Environmental Science and Pollution Research, 2022, 29, 23767
    81. S. M. Pourkiaei, M. H. Ahmadi, M. Sadeghzadeh, S. Moosavi, F. Pourfayaz, L. Chen, M. A. Pour Yazdi and R. Kumar, Energy, 2019, 186, 115849
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