| Citation: |
Wannuo Li, Qian Yang, Doudou Liang, Jun Zhi, Yucen Liu, Qijie Wu, Long Zhang, Shun Li, Jianming Zhang, Yuqiao Zhang. Electrochemical control ionic defects modulation induced phase transition in SrCoOx: progress and prospect[J]. Materials Lab, 2024, 3(2): 230030. doi: 10.54227/mlab.20230030
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Electrochemical control ionic defects modulation induced phase transition in SrCoOx: progress and prospect
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Abstract
Transition metal oxides (TMOs), as one of the advanced materials, have been widely studied due to their unique electronic, magnetic, optical, and thermal transport properties. Among them, SrCoO
x (SCOx ) is known as an oxygen sponge, where the ordered one-dimensional oxygen vacancy channels in the structure can work as the pathway for hydrogen/oxygen ions migration, facilitating the modulation of oxygen stoichiometry through the topotactic redox reaction. In this way, a “multi-state” phases transition with tunable physical properties can be realized. In this review, we summarize recent research progress in the utilization of H+ and O2− ions to induce distinct phase transitions in SCOx , which result in obvious physical property changes. The ability to control the properties of SCOx over a wide range through the incorporation of ionic defects provides a promising route for the development of advanced functional devices. -
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Author Biographies
Wannuo Li graduated from Northeast Agricultural University in 2022 and is currently a graduate student at Jiangsu University. Her research interests are fabrication of high quality epitaxial thin film and advanced functional devices. 
Qian Yang received her master degree in chemical science and engineering, and Ph.D degree in Electronics for Informatics from Hokkaido University (Japan). She awared a JSPS Fellowship for Young Scientists from 2021 to 2022. Her research interests include advanced fabrication technics of high quality epitaxial thin films, topotactic phase transition materials, electrochemical redox and protonation, and solid-state thermal transistor. -
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Wannuo Li, Qian Yang, Doudou Liang, Jun Zhi, Yucen Liu, Qijie Wu, Long Zhang, Shun Li, Jianming Zhang, Yuqiao Zhang. Electrochemical control ionic defects modulation induced phase transition in SrCoOx: progress and prospect[J]. Materials Lab, 2024, 3(2): 230030. doi: 10.54227/mlab.20230030
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Figure 1.
Topotactic crystal structure change. BM-HxSCO2.5 is transparent weak ferromagnetic insulator, BM-SCO2.5 is a brown antiferromagnetic insulator, and PV-SCO3 is a black ferromagnetic metal.
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Figure 2.
Electrochemical induced H+ evolution in SrCoOx structure. a Schematic illustrations of oxidation/protonation process of SrCoO2.5 by using water containing ionic liquid electrolyte.[13] Copyright 2017, Springer Nature. b Topotactic phase transitions of SrCoOx during electrochemical protonation/oxidation process. Multi-phase transition (H2SCO2.5
$ \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over{\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} $ $ \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over{\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} $ $ \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over{\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} $ $ \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over{\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} $ -
Figure 3.
a Schematic structure of electrochemical cell using 12CaO·7Al2O3 (CAN) film as the solid electrolyte. b Out-of-plane XRD patterns. When applying a positive voltage, HxSrCoO2.5 formed, whereas a negative voltage caused the conversion of SrCoO2.5 to SrCoO3.[40] Copyright 2021, American Chemical Society.
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Figure 4.
Schematic device structure composed of SrCoO2.5, leakage-free electrolyte, and a proton absorber layer. The role of the leakage-free electrolyte is to absorb water from the air, generating OH− ions for the oxidation reaction.[46] Copyright 2017, AIP Publishing.
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Figure 5.
a Oxidation current with different electron density was applied to the multilayer structure composed of Pt/YSZ/GDC/SrCoO2.5/Al at 300 °C in air as shown in the inset. SrCoOx samples with different oxidation states were prepared.[52] Copyright 2019, Wiley-VCH. b Macroscopic mapping of the insulating SCO2.5 region (blue part) and the conducting SCO3−x region (yellow part) was observed by conductive AFM.[52] Copyright 2019, Wiley-VCH. c Schematic structure of a solid-state electrochemical thermal transistor. The on-off state was controlled by phase transition from SrCoO3 and SrCoO2, respectively.[20] Copyright 2023, Wiley-VCH. d Repeatable changes in the thermal conductivity of the SrCoOx layer.[20] Copyright 2023, Wiley-VCH.
